Preheat oven to 350F. Grease two 8-inch round cake pans. Line with parchment paper and lightly spray top of parchment.
Into the bowl of a stand mixer or a large bowl if using a hand mixer, sift the flour, sugar, cocoa powder, baking soda, baking powder and salt. Mix on low speed with the paddle attachment until combined.
In a medium bowl, combine the buttermilk, eggs, yolk and vanilla. Slowly add the wet ingredients to the dry ingredients with the mixer running on low.
Continue mixing on low and slowly add the hot coffee until just combined. Turn off the mixer and scrape the bottom and sides of the bowl. Mix again briefly to ensure an even mixture.
Pour the batter into the prepared pans and bake for 35 to 40 minutes, or until the center springs back when lightly touched and a cake tested comes out clean. Cool in the pans for 15 minutes and then remove from pans. Cool on a cooling rack until completely cooled.